I consider their "meet cute" to be about 3/4 through the first episode, when she learns he's co-opted her con when her client announces that he(he told her he was a government agent investigating...well, himself, but she already had her serious suspicions) is Remington Steele...and she chews him out in a seething whisper and he knows the only reason she didn't kill him then and there(probably by taking off her high healed shoes and stabbing him in the heart with one of the heals) was because she was far too classy and refined-not to mention smart-to commit murder in a crowded room of potential clients.